carbon and its compound important question
Question.2 What is the
difference in the molecular formula of any two consecutive members of a
homologous series of organic compounds?
Answer. —CH2— is the difference in
the molecular formula of any two consecutive members of a homologous series of
organic compounds.
Question.3 very very
important
(a) Give a chemical test to distinguish between saturated and unsaturated
hydrocarbons.
(b) (i) Name the products formed when ethanol burns in air. ‘
(ii) What two forms of energy are liberated on burning alcohol?
(c) Why is the reaction between methane and chlorine considered a
substitution
reaction?
Answer.
Question.4
(a) Why are covalent compounds generally poor conductors of electricity?
(b) Name the following compound:
(c) Name the gas evolved when ethanoic acid is added to sodium carbonate. How
would you prove the presence of this gas?
Answer.
Question.5 Name the
carbon compound which on heating with excess of concentrated
sulphuric acid at 443 K gives ethene.
Answer.
Question.6 What is
meant by a sturated hydrocarbon?
Answer. Those hydrocarbons in w hich valency of carbon is satisfied
by single bonds only are called sturated hydrocarbons.
Question.7 Name the
compound formed when ethanol is warmed with ethanoic acid in the
presence of a few drops of cone.H2S04
Answer.
Question.8 Draw the
structure of CH3COOH molecule.
Answer.
Question.9 Draw the
structure of ethanol molecule.
Answer.
Question.10 What
happens when a small piece of sodium is dropped into ethanol?
Answer. Hydrogen gas will be evolved.
Question.11 What is
meant by a functional group in an organic compound? Name the functional group
present in
(i) CH3CH2OH
(ii) CH3COOH
Answer.
(a) Functional group is an atom or group of atoms or reactive part of compound,
which determines chemical properties of compounds.
(i) —OH (Alcohol)
(ii) —COOH (Carboxylic acid)
Question.12 Give reasons for the following observations:
(a) The element carbon forms a very large number of compounds.
Answer.
(a) Carbon forms large number of compounds since carbon is small in size and
can form stable covalent bonds (catenation) and it shows tetravalency.
Question.13 What is ethanoic acid? Write the formula of the functional group
present in this acid.
What special name is given to its 5 – 8% solution in water? How does
ethanoic acid react with sodium carbonate? Write a chemical equation of the
reaction and common name of the salt produced.
Answer.
Question.14 State two
characteristic features of carbon which when put together give rise to large
number of carbon compounds.
Answer. (i) Catenation (ii) Tetravalency of carbon
Question.15 Write the
structural formula of chloroethane.
Answer.
Question.16 Write the
name and molecular formula of an organic compound having its name suffixed with
‘-ol and having two carbon atoms in the molecule. With the help of a
balanced chemical equation indicate what happens when it is heated with
excess of r cone.H2So4.
Answer.
Question.17 Write the
names and molecular formula of two organic compounds having functional r group
suffixed as ‘-oic acid’. With the help of a balanced chemical equation and
explain what happens when any one of them reacts with sodium hydroxide.
Answer.
Question.18 What is a
homologous series? Which two of the following organic compounds belong
to the same homologous?
CH3 ,C2H6, C2H6O,
C2H6O2,CH4O
Answer.
Question.21 An organic
compound ‘A’ is an essential constituent of wine and beer. Oxidation of ‘A’
yields an organic acid ‘B’ which is present in vinegar. Name the compounds ‘A’
and ‘B’ and write their structural formula. What happens when ‘A’ and ‘B’ react
in the presence of an acid catalyst? Write the chemical equation for the reaction.
Answer.
Question.22 What is
ethanol? State its two properties. What happens when it is heated with
excess of cone. H2SO4 at 443 K? What role does
cone. H2SO4 play in this reaction? Write chemical
equation of the reaction involved and the structural formula of the main
product formed.
Answer.
Question.24 How many
covalent bonds are there in a molecule of ethane (C2H6)?
Answer. There are 7 covalent bonds in a molecule of ethane.
Question.25 Write the
electron dot structure of ethene molecule (C2H4).
Answer.
Question.26 Write the
electron dot structure of ethane molecule (C2H6).
Answer.
Question.27 Draw the
structure of butanone molecule, CH3COC2H5.
Answer.
Question.28 Draw the structure of the hexanal
molecule, C5H11CHO.
Answer.
Question.29 Butanone
is a four carbon per molecule compound. Name the functional group
present in it.
Answer. Ketone
Question.30 Name the following compound:
Answer. 1-Hexyne is IUPAC name of the compound.
Question.31 What is an ‘esterification’ reaction? Describe an
activity to show esterification. Very IMPORTANT
Answer.
Question.32 Out of HCI
and CH3COOH, which one is a weak acid and why? Describe an activity
to
support your answer.
Answer. Acetic acid ( CH3COOH) is a weaker acid because
it does not dissociate completely into its ions in aqueous solution.
Activity: Add zinc metal in HCI and CH3COOH respectively. The
hydrogen gas will be evolved faster in HCI and slowly in CH3COOH. It
shows acetic acid is a weak acid.
Alternative Method:
If we use pH paper, the colour of pH paper will be dark red in HCI and light
red in CH3COOH which shows HCI is a strong acid and CH3COOH
is a weak acid.
IMP
Question.33Write chemical
equations for what happens when
(i) sodium metal is added to ethanoic acid.
(ii) solid sodium carbonate is added to ethanoic acid.
(iii) ethanoic acid reacts with a dilute solution of sodium hydroxide.
Answer.
Question.34 Describe two
examples of different oxidations of ethanol. Name the products obtained in each
case.
Answer.
Question.36 (a) In tabular
form, differentiate between ethanol and ethanoic acid under the following
heads:
(i) Physical state (ii) Taste
(iii) NaHCO3 test (iV) Ester test
(b) Write a chemical reaction to show the dehydration of ethanol.
Answer.
Question.37 (a) State
two properties of carbon which lead to a very large number of carbon compounds.
Answer.
(a) (i)-Catenation (ii) Tetravalency
Question.38 Explain
isomerism. State any four characteristics of isomers. Draw the structures of
possible isomers of butane, C4H10
Answer. Isomerism is a phenomenon due to which
some compounds have same molecular formula but different structural formulae.
Characteristics:
(i) They differ in structural formula.
(ii) They differ in melting point.
(iii) They differ in boiling point.
(iv) They differ in solubility in same solvent.
Question.39 Give reasons
for the following:
(i)Element carbon forms compounds mainly by covalent bonding.
(ii)Diamond has a high melting point.
(iii)Graphite is a good conductor of electricity.
(iv)Acetylene bums with a sooty flame.
(v)Kerosene does not decolourise bromine water while cooking oils do.
Answer.
(i) It is because carbon has four valence electrons, it cannot gain or lose
four electrons because high energy is needed. It can only share four electrons.
(ii) It is due to strong covalent bonds and compact structure of diamond.
(iii) It is due to presence of free electrons in graphite because each carbon
is linked to three more carbon atoms.
(iv) It is due to high percentage of carbon, it burns with sooty or smoky flame.
(v) Kerosene oil is mixture of saturated hydrocarbons therefore does not
decolourise bromine water.
Question.40 Name the
functional group present in each of the following organic compounds:
(i) C2H5CI
(ii) C2H5OH
Answer.
(i) (—Cl) Halogen (Chloro)
(ii) (—OH) Alcohol
Question.47 Write the
name and formula of the 2nd member of the series of carbon compounds whose
general formula is CnH2n.
Answer.
C3H6, H2C=CH—CH3
Propene is second member of series whose general formula is CnH2n.
Question.48 What are
isomers? Draw the structures of two isomers of butane, C4H10.
Why can’t we have isomers of first three members of alkane series?
Answer. Those compounds, which have same molecular formula but
different structural formulae are called isomers.
In first three members of alkane series, branching is not possible. Therefore,
we cannot have isomers.
Question.49 Define
homologous series of organic compounds. List its two characteristics. Write the
name and formula of the first member of the series of alkenes.
Answer. The series of organic compounds having same functional group
and similar chemical properties is called homologous series.
Each member differs from successive member by —CH2— group. The
difference in molecular weight between two successive members is 14 u.
Characteristics:
(i) It has same general formula, from which, all members can be derived.
(ii) They have similar chemical properties.
C2H4, CH2=CH2, Ethene is first
member of alkene series.
Question.50 Complete
the following equations:
Answer.
Question.51 Why homologous
series of carbon compounds are so called? Write chemical formula of two
consecutive members of a homologous series and state the part of these
compounds that determines their
(i) physical properties, and (ii) chemical properties.
Answer. The series consists of members of same
family with similar physical and chemical properties, therefore, called
homologous series
(i) CH3OH, and (ii) CH3CH2OH are two consecutive
members of homologous series.
Alkyl group —CH3 and —CH3CH2 part
determines physical properties. Functional group —OH determines chemical
properties of the compounds.
Question.52 Name the
oxidising agent used for the conversion of ethanol to ethanoic acid.
Distinguish between ethanol and ethanoic acid on the basis of (i) litmus test,
(ii) reaction with sodium hydrogencarbonate.
Answer. Alkaline potassium permanganate or
Acidified potassium dichromate.
(i)Ethanol will not affect litmus paper. Ethanoic acid will turn blue litmus ‘
paper red.
(ii) Ethanol will not react with sodium hydrogen carbonate. Ethanoic acid will
give brisk effervescence due to colourless, odourless carbon dioxide gas.
Question.53 Distinguish
between esterification and saponification reactions of organic compounds with
the help of the chemical equation for each. What is the use of (i) esters and
(ii) saponification process?
Answer.
Question.55 List in
tabular form three physical and two chemical properties on the basis of which
ethanol and ethanoic acid can be differentiated
Answer.
Question.56 What are the
hydrocorbons write the name and general formula of (i) sturated hydrocarbons,
(ii) unsaturated hydrocarbons, and draw the structure of one hydrocarbon of
each type. How can an unsaturated hydrocarbon be made saturated?
Answer.
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